Submarine Groundwater Discharge Research Articles

Radionuclides in marine sediment

Abstract Most contaminants in the sea originate from land sources. Radionuclides in sea water are transported by sea currents. Marine sediment is a physical trap for pollutants that are introduced to the environment and play an important role in radiological studies. Radionuclides from seawater bound to particulates sink to the seabed. Their resuspension causes the reintroduction of pollutants to the water column. Remobilization and horizontal/vertical transport by various processes may occur. Long-lived radionuclides become buried in sub-surface sediment. Grain size sediment classification and sediment geochemical composition all play a significant role in the development of the radionuclide content of marine sediment. Atmospheric fallout from the Chernobyl and the Fukushima accidents, atmospheric nuclear weapon testing, releases from nuclear industry plants, river runoff, and to a lesser extent directed and submarine groundwater discharges are the major sources of radionuclides in the marine environment.

Groundwater mapping of urban and coastal areas in Brunei

Groundwater mapping plays an important role in effective water resource management, sustainable development, and environmental protection. In the tropical Brunei Darussalam (north Borneo Island), groundwater mapping is yet to be provided. The aim of the study is to provide groundwater mapping of Brunei, particularly for the urban and coastal areas of the Brunei-Muara capital district. The study uses a GIS interpolation technique to generate a groundwater contour map based on groundwater data from 572 sacrificial boreholes located in the study area. Remote sensing data and published maps from secondary sources were digitised in ArcGIS software to produce thematic layers for further hydrological evaluations. Results showed that groundwater levels in the study area are generally high and shallow, ranging from 0 to 18 m below ground level with a mean value of 2.9 m. According to the evaluation of geo-thematic layers and groundwater contours, groundwater flows towards the South China Sea in the coastal areas and towards the Brunei River further inland. Hydraulic gradients towards the South China Sea also vary between 0.004 and 0.08. Thus, assuming surface aquifer thickness in the weathered zone between 10 to 20 m, hydraulic conductivities ranges from 1∙10−5 to 1∙10−4 m∙s−1, a submarine groundwater discharge (SGD) flux between 4.7∙10−7 to 4.0∙10−4 m3∙s−1 per unit width can be estimated for the shallow aquifer. This study provides valuable insights into the groundwater system dynamics so important, which are critical for its future utilisation and protection, aiming to contribute to the national water security in Brunei Darussalam.

SGD-OD: investigating the potential oxygen demand of submarine groundwater discharge in coastal systems

Submarine groundwater discharge (SGD) supplies nutrients, carbon, metals, and radionuclide tracers to estuarine and coastal waters. One aspect of SGD that is poorly recognized is its direct effect on dissolved oxygen (DO) demand in receiving waters, denoted here as SGD-OD. Sulfate-mediated oxidation of organic matter in salty coastal aquifers produces numerous reduced byproducts including sulfide, ammonia, dissolved organic carbon and nitrogen, methane, and reduced metals. When these byproducts are introduced to estuarine and coastal systems by SGD and are oxidized, they may substantially reduce the DO concentration in receiving waters and impact organisms living there. We consider six estuarine and coastal sites where SGD derived fluxes of reduced byproducts are well documented. Using data from these sites we present a semiquantitative model to estimate the effect of these byproducts on DO in the receiving waters. Without continued aeration with atmospheric oxygen, the study sites would have experienced periodic hypoxic conditions due to SGD-OD. The presence of H2S supplied by SGD could also impact organisms. This process is likely prevalent in other systems worldwide.

Detecting changes in seafloor elevation in sandy coastal environments using low-cost opensource tooling

Knowledge of sediment erosion and deposition can be useful for a variety of engineering, marine science, and environmental applications, but collecting detailed time-series measurements of the sediment–water interface can be challenging, particularly in coastal marine environments. We developed economical and open-source sediment level loggers to record sediment–water interface time-series data with accuracy up to 1 cm. The logger is composed of a programmable Circuit-Python (or Arduino) microcontroller and “breakout boards” that attach to a specially designed printed circuit board (PCB) and an array of evenly spaced photoresistors enclosed in a robust waterproof housing. These instruments were paired with temperature sensors in a study off the coast of Charleston, SC in the South Atlantic Bight where heat was used as a tracer to detect the flow of porewater in the permeable coastal sediments. This approach requires accurate knowledge of the depth of temperature sensors relative to the sediment–water interface. In this application, improved knowledge of the elevation of the sediment–water interface elevation data from the sediment level loggers reduced average root mean squared errors in modeling submarine groundwater discharge by as much as 25 %. The sediment level loggers can be easily installed, withstand long deployment times, and provide long-term recording abilities suitable for a range of environments.

Flow and Transport in Coastal Aquifer‐Aquitard Systems: Experimental and Numerical Analysis

AbstractCoastal aquifers are commonly layered, and thus, a clear understanding of groundwater flow and salt transport in layered coastal aquifers is important for managing fresh groundwater. However, the influence of leakage between adjacent aquifers on flow and transport processes remains largely unknown where the influence of tides is considered. This study used laboratory experiments and numerical simulation to examine the processes of flow and transport within a tidal aquifer‐aquitard system (i.e., an unconfined aquifer underlain by a semi‐confined aquifer, with an intervening thin aquitard). The laboratory‐scale observations of the current study are the first observations of offshore fresh groundwater within a semi‐confined coastal aquifer. The numerical and laboratory results are in close agreement, revealing that upward leakage from the semi‐confined aquifer into the saltwater wedge of the overlying unconfined aquifer caused buoyant instabilities to form. The development of freshwater fingers created complex saltwater‐freshwater mixing, leading to mixed saltwater influx‐efflux patterns across the sloping aquifer‐ocean interface. Compared with non‐tidal conditions, tidal forces reduced the net upward leakage from the semi‐confined aquifer to the overlying unconfined aquifer. This increased the horizontal flow toward the sea, which in turn reduced the extent of the saltwater wedge in the semi‐confined aquifer. The higher rates of both fresh and saline submarine groundwater discharge (SGD), caused by tides, led to lower groundwater ages in the semi‐confined aquifer. These findings have important implications for unveiling the complex characteristics of seawater intrusion, SGD and geochemical hotspots within layered coastal aquifers.

Zone-specific longshore sampling as a strategy to reduce uncertainties of SGD-driven solute fluxes from high-energy beaches

Submarine groundwater discharge (SGD) from intertidal beach systems forms a source of fresh and saline, often nutrient-enriched water to the near-shore across the world. The chemical composition of solute flux via SGD depends on several factors, including solid phase composition, organic matter supply, hydraulic gradients, as well as pore water residence time and origin, which are partly related to the beach topography. High-energy sandy beaches are especially prone to frequent sediment relocation and a variable topography, often characterized by a ridge and runnel structure. Topography may not only change on a temporal scale, but also in the longshore direction, which may alter SGD-driven solute fluxes. However, sampling high-energy beach sites is challenging and often does not allow for high resolution cross- and longshore sampling. We tested the approach of zone-specific pore water sampling, whereby samples were taken at the high water line, in the runnel, on top of the ridge, and close to the low water line of eight cross-shore transects. This was done in order to assess the longshore variability of pore water composition and flux over a 2.5 km wide beach section. In this study we relied on relatively few data points per transect and still found a characteristic cross-shore distribution of pore water parameters, related to redox conditions of each zone. Recharge zones (high water line and ridge) exhibited higher O2 and NOx concentrations and discharge zones (runnel and low water line) exhibited higher nutrient, DOC, Mn, and Fe concentrations. Furthermore, DOC concentrations in pore waters were lower than in coastal seawater, supporting previous assumptions of rapid organic matter turnover. Nevertheless, we observed large concentration ranges among samples assigned to the same zone, which could partly be related to longshore topography differences. The measured pore water concentrations and calculated SGD-driven solute fluxes indicated that sampling of single cross-shore transects may be representative for a beach section when assessing a redox-independent parameter like Si, while it is less representative for parameters affected by more complex biogeochemical processes like P, NH4, Mn, and Fe. For these, we suggest that longshore distributed data coverage combined with higher resolution sampling in discharge zones is a good strategy to reduce the uncertainty associated with estimating SGD-driven solute fluxes in a practicable way.

Phytoplankton abundance and biodiversity in adjacent estuaries: the importance of submarine groundwater discharge

AbstractA near-unique pair of adjacent bays in the karst region of western Ireland provided the opportunity to compare phytoplankton diversity and abundance in an area of submarine groundwater discharge (SGD) side by side with a ‘control’ region of similar size and with the same marine influences. Freshwater input to Kinvara Bay comes from the surrounding karst hinterland via a subterranean groundwater network, emerging at several sites within the inner bay as submarine groundwater discharge (SGD). Aughinish Bay in contrast has no connection to a SGD network and negligible overground fresh water input. Sampling was carried out in both bays during spring and neap tides over Winter, Spring/Summer and Summer/Autumn of 2016 and 2017. Comparison of the phytoplankton communities in the two bays showed higher diversity in Aughinish, while a bloom of Prorocentrum micans (Ehrenber, 1834), a brackish-water-tolerant marine dinoflagellate, was observed only in Kinvara. This work demonstrates how SGD can control phytoplankton community structure even in well-flushed macro-tidal bays and thus controls the biogeography at local scales.

Variability of the trophic state in a coastal reef system associated with submarine groundwater discharge in the Mexican Caribbean.

Submarine groundwater discharges (SGD) have been associated with important sources of nutrients between the land and oceans that can generate eutrophication conditions. This study aims to analyze the behavior of nitrogen and phosphorus using the mixing curve method, to examine the variation of the trophic state using the Karydis Index, and to evaluate the δ15N in benthic organisms to trace the origin of nitrogen in neap tide (November) and spring tide (January) in the Manatí Cenote, and Nohoch-Teek reef lagoon in the Mexican Caribbean. Nitrogen and phosphate enrichment was in the Manatí Cenote during neap and spring tides. This enrichment was particularly noticeable in the reef lagoon during low tides in the areas influenced by SGD. In the Cenote, differences in the nitrate trophic state were observed, indicating an eu-mesotrophic condition during neap tide and a mesotrophic condition during spring tide. However, no significant differences were observed for ammonium (oligo-mesotrophic), nitrites, or phosphate compounds (oligotrophic). The trophic state reef lagoon exhibited a similar pattern but with different spatial variations. In both systems, phosphorus was a limiting nutrient, while δ15N suggested anthropogenic nitrogen uptake by several benthic organisms.

Synergistic controls of water column stability and groundwater phosphate on coastal algal blooms

Algal blooms have been identified as one major threat to coastal safety and marine ecosystem functioning, but the dominant mechanism regulating the formation of algal blooms remains controversial, ranging from physical control (via water column stability), the chemical control (via coastal nutrients) to joint control. Here we leveraged the unique data collected in the Hong Kong water over the annual cycle and past three decades, including direct observations of algal blooms and coastal nutrients and process model output of water column stability, and evaluated the differential competing hypotheses in regulating algal blooms. Our results demonstrate that the joint mechanism rather than the single mechanism effectively predicts all algal blooms. Meanwhile, we observed that the adequate nutrients (phosphate, PO43−) significantly originate from coastal groundwater. The production and fluctuation of PO43− in beach aquifers are primarily governed by groundwater temperature, leading to a sustained and sufficient supply of PO43− in a low groundwater temperature environment. Furthermore, along with submarine groundwater discharge (SGD), the ongoing release of PO43− in groundwater enters coastal waters and serves as sufficient nourishment for promoting algal blooms in coastal areas. These results highlight the importance of both physical and chemical mechanisms, as well as SGD, in regulating coastal algal blooms. These findings have practical implications for the prevention of coastal algal blooms and provide insights into mariculture, water security, and the sustainability of coastal ecosystems.

Tracing the contributions of different nitrate sources associated with submarine groundwater discharge in coastal seawaters off Jeju Island, Korea

We measured the concentrations of dissolved inorganic nutrients and the dual isotopic composition of nitrate (δ15N-NO3− and δ18O-NO3−) in coastal waters off Jeju, a volcanic island in Korea, to trace its main sources. Sampling of seawater and fresh groundwater was conducted in four different coastal areas of Jeju Island: Haengwon (HW), Pyoseon (PS), Ilgwa (IG), and Sagye (SG) in May 2020 and 2021. The significant negative correlations between NO3− and salinity in the four areas indicate that the main source of NO3− is fresh submarine groundwater discharge (FSGD), with the extrapolated fresh groundwater endmember values ranging from 170 to 300 μM (δ15N-NO3−: 4.1–10.8 and δ18O-NO3−: 1.7–6.4). The actual sources of SGD-driven NO3− in these coastal waters were determined using a bi-plot diagram (δ15N-NO3− vs. δ18O-NO3−) and a Bayesian stable isotope mixing model (MixSIAR). The results showed that, besides the background contribution from open-ocean waters, the main sources of NO3− in HW were fertilizer (69 ± 5%) and manure and sewage (24 ± 7%) and those in PS, IG, and SG were manure and sewage (PS: 53 ± 11%, IG: 57 ± 12%, SG: 63 ± 13%) and fertilizer (PS: 27 ± 8%, IG: 24 ± 5%, SG: 22 ± 5%). Our extrapolation approach for NO3− dual isotopes provides a better way to evaluate the main sources of NO3− in coastal waters off volcanic islands where SGD-driven NO3− is significant, but its actual source groundwater cannot be located.

Anthropogenic activities alter the hydrological process of submarine groundwater discharge in a coastal area of Shanghai City, China

Submarine groundwater discharge (SGD) is recognised as a crucial factor influencing coastal ecosystems and biogeochemical processes. Anthropogenic activities not only discharge a large amount of nutrients and pollutants into oceans but also alter the hydrological processes of SGD. Changes in the recharge source and flow pathway of submarine groundwater under anthropogenic activities were revealed in this study by investigating the spatial and temporal isotopic, geochemical and hydrometric characteristics of various water types. The interaction between salt water and fresh water in the intertidal zone was also explored based on the law of isotopic mass conservation and the model of end-member mixing. Our results indicated that the shallow groundwater at depths of 4 m and 13 m is mainly recharged by local precipitation. The fresh submarine groundwater, river water, lake water and terrestrial groundwater at depths of 23 m and 60 m are largely recharged by the Yangtze River. The fresh submarine groundwater is mainly affected by artificially recharged with water from the Yangtze River, and its recharge pathway is relatively deep due to the impact of dam construction. Seawater contributes to more than 60 % of the SGD in most intertidal zones through the discharge processes of mixed salt water and seawater in the upper saline plume. Our study contributes to an improved understanding of anthropogenic impacts on SGD and has crucial implications for accurately tracing and quantifying the hydrological processes of SGD.

Coastal flowing artesian wells and submarine groundwater discharge driven by tidal variation at TaiCOAST site in Taoyuan, Taiwan

Study regionThis study was conducted at the TaiCOAST site, Taoyuan City, Taiwan. Study focusThree coastal flowing artesian wells (FAWs) were observed at the TaiCOAST site that do not match the well-known driving mechanisms of geological or topographical control. The observed phenomenon has not been discussed in the literature. This study collected hydraulic head data for the three coastal FAWs and one onshore well at the TaiCOAST site. A multi-phase (freshwater and seawater) model of groundwater in porous media was constructed to investigate the mechanism of the coastal FAWs and quantify submarine groundwater discharge (SGD). New hydrological insights for the regionThe rare observations of coastal FAWs at the TaiCOAST site were found to be neither geologically, topographically, nor recharge controlled. The constructed numerical model indicates that the coastal FAWs are driven by an upward flow due to the sharp interface between freshwater and seawater, which acts as a barrier. The depth profile of Darcy’s velocity was obtained from the calibrated model. The average Darcy’s velocity of SGD is (2.96 ± 0.61) × 10−6 m/s, which is similar to value reported in the literature. This study provides new insight into the mechanism of FAWs in coastal areas. The results can serve as an important reference for investigations of SGD.

Production and fluxes of inorganic carbon and alkalinity in a subarctic subterranean estuary

In this study, we focus on the biogeochemical processes that produce both dissolved inorganic carbon (DIC) and total alkalinity (TA) along a subarctic subterranean estuary (STE) located in the Gulf of St. Lawrence (Magdalen Island, Qc, Canada) in order to evaluate the DIC and TA fluxes as well as the buffering capacity of the exported groundwater to coastal waters. DIC and TA do not behave conservatively during mixing along the groundwater flow path and this implies the occurrence of internal redox reactions that control both their production and consumption. In addition, we show that the origin and composition of the organic carbon within the system alter the carbonate parameters by generating low pH conditions (5.9 - 7.2) and contributing to non-carbonate alkalinity (NCA) that accounts for more than 30% of TA. Whereas iron cycling plays a key role in the production of DIC in the fresh and low-salinity groundwaters, the precipitation of sulfide minerals neutralize the acidity produced by the metabolically produced CO2, in the saline groundwater where sulfate is available. The STE pCO2, computed from the DIC-pHNBS pair ranged from a few ppm to 16000 ppm that results in a CO2 evasion rate of up to 310 mol m−2d−1 to the atmosphere. Based on Darcy flow and the mean concentrations of DIC and carbonate alkalinity (Ac = TA - NCA) in the discharge zone, fluxes derived from submarine groundwater discharge were estimated at 1.43 and 0.70 mol m−2d−1 for DIC and Ac, respectively. Despite a major part of the metabolic CO2 being lost along the groundwater flow path, the SGD-derived DIC flux was still greater than the Ac flux, implying that groundwater discharge reduces the buffering capacity of the receiving coastal waters. This site-specific scale study demonstrates the importance of diagenetic reactions and organic matter remineralization processes on carbonate system parameters in STE. Our results highlight that subarctic STEs could be hot spots of CO2 evasion and a source of acidification to coastal waters that should be considered in carbon budgets.

Fresh and recirculated submarine groundwater discharge zones along the central west coast of India

The study area receives an average of 2840.0 mm of rainfall within four months every year. A portion of the rainwater is flown to the sea as surface water, and the other part is percolated into the bottom as groundwater. In coastal aquifers, the groundwater is transported to the sea due to a hydraulic gradient, and it contains a significant quantity of dissolved materials and nutrients. SGD processes impact the ocean productivity, mangrove and coral growth, local acidification and many. To isolate the SGD on the central west coast of India, different data was referred. The GWL concerning MSL contributed significantly to demarcating the SGD zones by considering the positive (>0 m) and negative (<0 m) values of GWL concerning above MSL. Thermal images for SST of pre-monsoon and post-monsoon periods of 2020 exhibit cooler surrounded by warmer, which might be the SGD buffering zones in the off-central west coast of India. By considering the results from GWL and SST, 8 SGD beach sites were identified for the further particularized study. The water samples were collected in March 2022, and analyzed using standard procedures and instruments. Fresh and mixing (recirculated) zones have been isolated by piper, hydrochemical facies evolution, and Ca2++Mg2+/K++Na + Vs log Cl− ionic ratio plots. The aquifer water chemical elements are converting possibly due to ionic exchange processes. The decrease in salinity and conductivity observed in the pore water just below the seawater might be due to the influence of freshwater inputs, helping to isolate the fresh SGD and recirculated SGD zones in the study area. Among 8 sites, 3 were found to be fresh SGD sites and 5 were noticed to be mixing/recirculated SGD sites. Most of these Beaches are bounded by hills, which helps to lead the SGD along the central west coast of India.

A comprehensive analysis of submarine groundwater discharge and nutrient fluxes in the Bohai Sea, China

Groundwater discharge and associated nutrient fluxes in the Bohai Sea, China has attracted great attention, but most studies lacked high spatial resolution for the whole sea. As the largest semi-enclosed sea in China, the Bohai Sea is confronted with strong environmental pollution problems such as eutrophication induced by terrestrial nutrient inputs. However, the role of SGD has not been evaluated well for the whole Bohai Sea. In this study, stable isotopes (hydrogen and oxygen), radioactive isotope (228Ra), salinity, and temperature were combined to trace the diluted seawater. Mass balances of 228Ra, oxygen isotope, and salinity were used to quantify SGD and nutrient fluxes to the Bohai Sea. The estimated submarine fresh groundwater discharge (SFGD) and SGD to the Bohai Sea were (6.0 ± 0.5) × 109 and (2.7 ± 1.6) × 1011 m3 a−1, respectively. SFGD represents 10 % to 11 % of the total river discharge and SGD is about 2 to 8 folds of the total river discharge to the sea. Moreover, SGD derived dissolved nutrients to the Bohai Sea were (4.8 ± 4.0) × 1010 mol a−1 for dissolved inorganic nitrogen, (1.9 ± 1.7) × 1010 mol a−1 for dissolved inorganic phosphorus, and (6.7 ± 5.5) × 1010 mol a−1 for silicon. These nutrient inputs were about 10 to 20 folds of the total riverine inputs. Overall, this study underscores the importance of evaluating SGD to better understand the terrestrial imported nutrients in regional scale.

The connection between Submarine Groundwater Discharge and seawater quality: The threat of treated wastewater injected into coastal aquifers

Submarine Groundwater Discharge (SGD) delivers nutrients to the coastal sea triggering phytoplankton blooms, eutrophication, and can also serve as a pathway for contaminants. Wastewater treatment plants (WWTP) including injection wells in coastal areas influence coastal aquifers and might impact the composition and magnitude of SGD fluxes. In tourist areas, wastewater treatment may be less efficient and larger in volume during high seasons, potentially impacting nutrient fluxes from SGD and exacerbating environmental impacts. This study analyzes the nutrient transfer from treated wastewater injection in karstic aquifers to the coastal sea via SGD, considering the impacts of tourism seasonality. This study is conducted in Cala Deià, a small cove in the Balearic Islands, a Mediterranean tourist destination. The findings suggest that the seasonality of tourism, leading to variations in the volume of wastewater treated in the WWTP, influences the dynamics of the coastal aquifer. This leads to increased SGD water and nutrient fluxes to the sea in summer, i.e. the peak tourist season. The measured DIN, DIP, and DSi inventories in the cove are much larger in August than in April (3, 10, and 1.5 times higher, respectively) due to higher input of nutrients in summer due to SGD impacted by the WWTP. These elevated nutrient flows can support algal blooms in the cove, compromising water quality for local swimmers and tourists. Indeed, in August, shoreline stations exhibited eutrophic Chl-a concentrations, with peaks reaching approximately 4 mg Chl-a L−1. These elevated levels suggest the presence of an algal bloom during the survey. The anthropogenic origin of SGD-driven nutrients is traced in seawater and seagrass meadows, as evidenced by high ∂15N signatures indicative of polluted areas. Thus, the high pressure exerted on coastal areas by tourism activities increased the magnitude of SGD nutrient fluxes, thereby threatening coastal ecosystems and the services they provide.

Submarine groundwater discharge into a semi-enclosed coastal bay of the southern Baltic Sea: A multi-method approach

The present study aims to understand the impact of submarine groundwater discharge (SGD) on a coastal area with different lithology and degrees of SGD. Sampling campaigns took place in Puck Bay and the Gulf of Gdańsk, southern Baltic Sea encompassing years between 2009 and 2021. The methodological approach combined geophysical characterization of the surface sediments with detailed spatial and temporal (isotope) biogeochemical investigations of pore and surface waters, and was supported by nearshore groundwater and river surveys. Acoustic investigations identified areas of disturbance that may indicate zones of preferential SGD release. The composition of porewater and the differences in the bay's surface waters disclosed SGD as common phenomenon in the study area. Regional SGD was estimated through a radium mass balance. Local estimation of SGD, based on porewater profiles, revealed highest SGD fluxes at the sandy shoreline, but relatively low elemental fluxes. Though SGD was low at the muddy sites corresponding elemental fluxes of nutrients and dissolved carbon exceeded those determined at the sandy sites due to intense diagenesis in the top sediments. SGD appears to be sourced from different freshwater endmembers; however, diagenesis in surface sediments substantially modified the composition of the mixed solutions that are finally discharged to coastal waters. Overall, this study provides a better understanding of the SGD dynamics in the region by a multi-approach and emphasizes the need to understand the processes occurring at the sediment-water interface when estimating SGD.

Optimizing groundwater radium end-members in submarine groundwater discharge estimation by incorporating groundwater flow information

Submarine groundwater discharge (SGD) can be as important as river discharge for marine ecosystems. Radium (Ra) isotopes are excellent tracers of SGD estimation, and the selection of groundwater radium end-members is the most critical step in using the radium mass balance model to evaluate SGD. However, where and when to collect groundwater Ra end-members and their relationship with groundwater flow were not fully considered in previous studies. Based on field investigations and numerical simulations, this study systematically analyzed the influence of groundwater flow on the spatial distribution of 224Ra activity, and a new method was proposed to determine groundwater Ra end-members by incorporating groundwater flow information in a sandy beach at Xiaojing Bay, China. The results show that the groundwater radium activity collected near the low tide mark at low tides may be the most suitable groundwater Ra end-member. Compared with the newly-proposed method, we found that the traditional methods for determining groundwater Ra end-members such as the mean value and quartile methods may overestimate the SGD rates. Our study provides new insights into the determination of groundwater Ra end-members in a tidal beach and highlights that the groundwater Ra end-members should be determined based on groundwater flow information in SGD estimations by radium mass balance model.

Dissolved carbon dynamics and exchange in a high permeability beach aquifer

The biogeochemical transformation of dissolved carbon in tidal beaches affects the coastal carbon cycle and budget. Yet, the influence of groundwater flow on the behavior of dissolved carbon and CO2 flux across the different interfaces in these dynamic beach systems remains poorly understood, especially in deep beach aquifers. In this study, we investigated the biogeochemical reactions and origins of dissolved carbon and quantitatively evaluated CO2 outgassing driven by submarine groundwater discharge (SGD) in a high permeability beach aquifer (9–13 m depth) located in the South China Sea shelf. Results revealed that both dissolved inorganic carbon (DIC) and total alkalinity (TA) exhibited non-conservative additions across the salinity gradient. The excess DIC and TA most likely resulted from organic carbon decomposition in the brackish and saline zones. Aerobic respiration (upper saline plume zone), anaerobic reactions, and tidal mixing were identified as the dominant processes controlling DIC and TA dynamics. The mean CO2 outgassing flux across the beach sediment-air interface was estimated to be 1.05 g m−2 d−1, significantly higher than the CO2 flux across the sea-air interface. The outgassing pattern of groundwater CO2 from beach aquifer appeared to be driven by tidal pumping. Considering the combined effects of SGD-derived dissolved carbon and nutrients, we suggest that SGD yielded a net CO2 flux, contributing to 45 % of the CO2 flux across the sea-air interface. SGD directly and indirectly delivered substantial CO2 from the beach aquifer to the atmosphere, approximately (4.89–9.21) × 103 tons of CO2 per year along the 76.2 km long sandy coast. These findings demonstrate that intertidal beach aquifers, as active biogeochemical reactors have the strong potential to intensify CO2 emissions to the atmosphere through both beach sediment-air and sea-air interfaces. This study provides a better understanding of the links between carbon biogeochemical cycles and hydrologic processes in the coastal zones.

Fresh and saline groundwater nutrient inputs and their impacts on the nutrient budgets in a human-effected bay

Submarine groundwater discharge (SGD) can be highly enriched in nutrients, especially in bays with strong human activity, but has often been overlooked in coastal nutrient budgets. This study investigated the impact of both fresh and saline SGD on nutrient budgets in Sanmen Bay, China, a region heavily influenced by human activities. Based on the 224Ra mass balance model, the total SGD flux was estimated to be (1.1 ± 0.1) × 108 m3 d−1 (13.9 ± 0.5 cm d−1). Additionally, a water-salt mass balance model revealed that fresh SGD flux accounted for ~9.0 % of the total SGD flux. The results highlight the significance of fresh SGD as a freshwater source, contributing to 35.9 % of the total dissolved inorganic phosphorus (DIP) flux via SGD. Considering all nutrient sources and sinks in the Sanmen Bay, SGD was identified as the primary source of nutrients in Sanmen Bay, contributing 53.9 % and 11.9 % of the total dissolved inorganic nitrogen (DIN) and DIP input, respectively. Furthermore, the discharge of industrial/domestic sewage and mariculture wastewater also posed a potential threat to nutrient levels in the bay. Thus, initiatives such as reasonable control of culture species and scale, strengthening wastewater discharge and SGD management are crucial for maintaining the ecological environment of the Sanmen Bay.